中国不同地区剩余臭氧及臭氧探空订正因子

郑向东; 田宏民; 刘梦琪

doi:10.11728/cjss2017.05.564

中国不同地区剩余臭氧及臭氧探空订正因子

doi: 10.11728/cjss2017.05.564

1. 中国气象科学研究院北京 100081;
2. 成都信息工程大学电子工程学院成都 610225

基金项目:

公益性气象行业专项项目资助（GYHY201106041）

详细信息

作者简介:
郑向东,E-mail:zhengxd@camscma.cn

中图分类号: P352
计量
- 文章访问数: 1040
- HTML全文浏览量: 41
- PDF下载量: 727
- 被引次数: 0
出版历程
- 收稿日期: 2016-09-21
- 修回日期: 2017-05-24
- 刊出日期: 2017-09-15

Residual Ozone and Ozonesonde Correction Factor over Different Sites of Chinaormalsize

1. Chinese Academy of Meteorological Sciences, Beijing 100081;
2. College of Electronic Engineering, Chengdu University of Information Technology, Chengdu 610225

摘要

摘要:
根据中国不同地点臭氧探空数据，研究气球炸点臭氧浓度定值（CMR）法、卫星（SBUV和MLS）纬向平均法确定的剩余臭氧Ω_res及其对订正因子C_ref的影响，同时检验臭氧垂直分布对C_ref的贡献.结果显示： CMR法对气球炸点高度依赖性明显，且易高估Ω_res使C_ref整体低于100%；卫星纬向平均Ω_res对气球炸点高度不敏感，但在中国东部的臭氧总量高值区或青藏高原及低纬度臭氧低值地区，Ω_res呈现近10DU以上低值，这是经向臭氧总量及其垂直分布差异在卫星遥感数据上的反映.地面到100hPa的对流层臭氧（Ω_tro），100~10hPa的平流层臭氧（Ω_str）以及10hPa以上的Ω_res对C_ref贡献平均分别为（16±3.4）%，（65±2.3）%，（19±3.3）%.表明基于C_ref评估或订正探空仪平流层臭氧测值时，需考虑对流层臭氧及确定Ω_res方法的影响.卫星纬向平均法，特别是近似实测的SBUV臭氧廓线的值适用于确定Ω_res.
- 臭氧探空 /
- 剩余臭氧 /
- 订正因子 /
- CMR法 /
- 卫星纬向平均
Abstract:
Residual ozone Ω_res is the integrated column ozone from the balloon bursting altitude, which is generally from 30~5hPa, to the top of atmosphere. The ozonesonde correction factor C_ref is the ratio of total column ozone Ω, which is precisely observed by ground or spacebased spectrophotometer, to the summery of Ω_ecc and Ω_res. Ω_ecc is the integrated ozonesonde data from ground to the balloon bursting altitude. C_ref is applied to assess and correct the stratospheric ozonesonde data with the well qualified Ω. Based on the sporadic Electrochemical Concentration Cell (ECC) ozonesonde data observed at different sites of China, Ω_res deduced by the Constant Mixing Ratio (CMR) and satellite zonal mean (including SBUV and MLS tables) are presented, and the impact of Ω_res on C_ref is investigated. The contributions of ozone vertical distribution to C_ref are also analyzed, and appropriate method to quantify Ω_res is proposed through the C_ref comparisons. Ω_res deduced by CMR method is sensitive to the balloon-bursting altitude, and is frequently overestimated. As a result, C_ref is generally less than 100%. Ω_res deduced by the satellite zonal mean method is not sensitive to the balloon-bursting altitude. However, C_ref is lower than about -10DU in two regions. One region is in east of China, such as Longfengshan in Heilongjiang province and Beijing, which is high total column ozone; the other region is Tibetan plateau and other low latitude districts including Hong Kong, which is low column ozone. The satellite zonally underestimated Ω_res reflects the longitude dependence of real atmospheric ozone over China. The tropospheric column ozone Ω_tro from the surface to 100hPa, stratospheric column ozone Ω_str from 100 to 10hpa and Ω_res to C_ref account 16%±3.4%, 65%±2.3%, 19%±3.3%, respectively. Therefore, it is necessary to consider the effects from Ω_tro and Ω_res on the evaluation or correction stratospheric ozone measured by ozonesonde if C_ref is used. The satellite zonal mean method is generally recommended, especially the Ω_res obtained when it is very close to the quasi real-time SBUV data. However, as the balloon bursting altitude above 10hPa, the conventional CMR method is also recommended for the two regions including north of east and north in China (winter and summer)-the high total ozone region, and Hong Kong (summer, autumn and winter), Tibetan plateau (summer) -the low total ozone region. It can weaken a system underestimation of C_ref if the satellite deduced Ω_res is used.
- Ozonesonde /
- Residual ozone /
- Correction factor /
- Constant Mixing Ratio (CMR) method /
- Satellite-zonal mean

HTML全文

参考文献(29)

[1]	BARNES R A, BANDY A R, TORRES A L. Electrochemical concentration cell ozonesonde accuracy and precision[J]. J. Geophys. Res., 1985, 90 (D5):7881-7887
[2]	JOHNSON B J, OLTMANS S J, VÖMEL H, et al. Electrochemical Concentration Cell (ECC) ozonesonde pump efficiency measurements and tests on the sensitivity to ozone of buffered and unbuffered ECC sensor cathode solutions[J]. J. Geophys. Res., 2002, 107 (D19):ACH 8-1-ACH 8-18. DOI: 10.1029/2001JD000557
[3]	HARRIS N, HUDSON R, PHILLIPS C. Assessment of Trends in the Vertical Distribution of Ozone, SPARC Report No.1, WMO Ozone Research and Monitoring Project Report No.43[R]. Geneva:SPARC, 1998
[4]	Science Pump Corporation. Operator's Manual Model 6A ECC OzoneSonde[R]. Camden, USA, 1996
[5]	TIAO G C, REINSE G C, PEDRICK J H, et al. A statistical trend analysis of ozonesonde data[J]. J. Geophys. Res., 1986, 91 (D12):13121-13136
[6]	WMO. Quality Assurance and Quality Control for Ozonesonde Measurements in GAW[R]. GAW Research and Monitoring Reports 201, Geneva:WHO, 2011
[7]	HILSENRATH E, ATTMANNSPACHER W, BASS A, et al. Results from the Balloon Ozone Intercomparison Campaign (BOIC)[J]. J. Geophys. Res., 1986, 91 (12):13137-13152
[8]	THOURET V, MARENCO A, LOGAN J A, et al. Comparisons of ozone measurements from the MOZAIC airborne program and the ozone sounding network at eight locations[J]. J. Geophys. Res., 1998, 103 (D19):25695-25720
[9]	DUTSCH H U. Two Years of Regular Ozone Soundings over Boulder, Colorado[R]. NCAR Technical Note NCAR/TN-10+STR, Boulder, Colo:NCAR, 1966
[10]	DOBSON G M B. Atmospheric ozone and the movement of the air in the stratosphere[J]. Pure Appl. Geophys., 1973, 106 (1):1520-1530
[11]	STÜBI R, LEVRAT G, HOEGGER B, et al. In-flight comparison of Brewer-Mast and electrochemical concentration cell ozonesondes[J]. J. Geophys. Res., 2008, 113 (D13):D13302. DOI: 10.1029/2007JD009091
[12]	MCPETERS R D, LABOW G J, JOHNSON B J. A satellite-derived ozone climatology for balloonsonde estimation of total column ozone[J]. J. Geophys. Res., 1997, 102 (D7):8875-8885
[13]	MCPETERS R D, LABOW G J. Climatology 2011:an MLS and sonde derived ozone climatology for satellite retrieval algorithms[J]. J. Geophys. Res., 2012, 117 (D10):D10303. DOI: 10.1029/2011JD017006
[14]	THOMPSON A M, MILLER S K, TILMES S, et al. Southern hemisphere additional ozonesondes (SHADOZ) ozone climatology (2005-2009):Tropospheric and Tropical Tropopause Layer (TTL) profiles with comparisons to OMI-based ozone products[J]. J. Geophys. Res., 2012, 117:D23301. DOI: 10.1029/2011JD016911
[15]	ZHOU Xiuji, LUO Chao, LI Weiliang, et al. Variations of total ozone amount in China and the ozone low center over Tibetan Plateau[J]. Chin. Sci. Bull., 1995, 40 (15):1396-1398(周秀骥, 罗超, 李维亮, 等. 中国地区臭氧总量变化与青藏高原低值中心[J]. 科学通报, 1995, 40 (15):1396-1398)
[16]	LIU Qijun, ZHENG Xiangdong, LUO Chao, et al. Ozone vertical profile characteristics over Qinghai Plateau measured by electrochemical concentration cell ozonesondes[J]. Adv. Atmos. Sci., 1997, 14 (4):481-490.
[17]	CUI Hong, ZHAO Chunsheng, QIN Yu, et al. An estimation of ozone flux in a stratosphere-troposphere exchange event[J]. Chin. Sci. Bull., 2004, 49 (2):167-174
[18]	CHAN C Y, ZHENG X D, CHAN L Y, et al. Vertical profile and origin of wintertime tropospheric ozone over China during the PEACE-A period[J]. J. Geophys. Res., 2004, 109 (D23):D23S06. DOI: 10.1029/2004JD004581
[19]	ZHENG Yongguang, CHEN Jiong, ZHU Peijun, et al. Influence of biomass burning in South Asia on lower tropospheric ozone concentration over Kunming[J]. Acta Sci. Nat. Univ. Pek., 2007, 43 (3):330-337(郑永光, 陈炯, 朱佩君, 等. 南亚地区生物体燃烧对昆明地区对流层中下层臭氧浓度的影响[J]. 北京大学学报(自然科学版), 2007, 43 (3):330-337)
[20]	YAN Xiaolu, ZHENG Xiangdong, ZHOU Xiuji, et al. Validation of aura microwave limb sounder water vapor and ozone profiles over the Tibetan plateau and its adjacent region during boreal summer[J]. Sci. China Earth Sci., 2015, 58 (4):589-603
[21]	FIOLETOV V E, TARASICK D W, PETROPAVLOVSKIKH I. Estimating ozone variability and instrument uncertainties from SBUV(/2), ozonesonde, Umkehr, and SAGE Ⅱ measurements:short-term variations[J]. J. Geophys. Res., 2006, 111 (D2):D02305
[22]	TRIPATHI O P, JENNINGS S G, O'DOWD C D, et al Measurements of stratospheric ozone at a mid-latitude observing station Valentia, Ireland (51.94°N, 10.25°W) using ground-based and ozonesonde observations from 1994 to 2009[J]. J. Atmos. Chem., 2013, 70 (4):297-316. DOI 10.1007/s10874-013-9274-5
[23]	ZHENG Xiangdong. Investigation on effect of cloud on the precision of total ozone from satellite measurements over China regions[J]. Chin. J. Atmos. Sci., 2008, 32 (6):1431-1444(郑向东. 云对中国区域卫星观测臭氧总量精度影响的检验分析[J]. 大气科学, 2008, 32 (6):1431-1444)
[24]	LABOW G J, MCPETERS R D, BHARTIA P K, et al. A comparison of 40 years of SBUV measurements of column ozone with data from the Dobson/Brewer network[J]. J. Geophys. Res., 2013, 118 (13):7370-7378
[25]	HENDRICK F, POMMEREAU J P, GOUTAIL F, et al. NDACC/SAOZ UV-visible total ozone measurements:improved retrieval and comparison with correlative ground-based and satellite observations[J]. Atmos. Chem. Phys., 2011, 11 (12):5975-5995
[26]	JEANNET P, STÜBI R, LEVRAT G, et al. Ozone balloon soundings at Payerne (Switzerland):reevaluation of the time series 1967-2002 and trend analysis[J]. J. Geophys. Res., 2007, 112 (D11):D11302. DOI: 10.1029/2005JD006862
[27]	MORRIS G A, LABOW G, AKIMOTO H, et al. On the use of the correction factor with Japanese ozonesonde data[J]. Atoms. Chem. Phys., 2013, 13 (3):1243-1260
[28]	SAKAZAKI T, FUJIWARA M, SHIOTANI M, et al. Diurnal Ozone Variations in the Stratosphere as Revealed with SMILES Observations, Quadrennial Ozone Symposium[R]. Troonto, Canada, 2012
[29]	PARRISH A, BOYD I, NEDOLUHA G, et al. Diurnal Variations of Stratospheric Ozone Measured by Ground-Based Microwave Remote Sensing at the Mauna Loa NDACC Site:Measurement Validation and Results, Quadrennial Ozone Symposium[R]. Troonto, Canada, 2012