Microstructure Evolution of Directionally Solidified Al-3.4%Bi Alloy
-
摘要: 对Al-3.4%Bi(质量分数)偏晶点成分合金开展了定向凝固实验,并对其凝固组织形成过程进行分析.结果表明,Al-Bi偏晶点成分合金定向凝固时在凝固界面前沿液相内形成溶质Bi富集层,并在该区域内发生液液相变.当试样凝固速度较慢时,合金凝固后弥散相粒子尺寸呈现双峰分布;当凝固速度较快时,凝固界面前沿所有尺寸的少量相液滴均向凝固界面迁移,合金凝固后弥散相粒子尺寸呈现单峰分布.Abstract: Directional solidification experiments are carried out with Al-3.4%Bi alloy and the microstructure evolution mechanism is investigated. The results demonstrate that a solute-rich layer forms in front of the solidification interface and the liquid-liquid decomposition occurs at the same region. When the alloy is solidified at a relatively low velocity, the size distribution of the minority phase particles shows two peaks. When the alloy is solidified at a high velocity so that the minority phase droplets of all sizes in front of the solidification interface migrate to the solidification interface, the size distribution of the minority phase particles shows only one peak.
-
[1] RATKE L, DIEFENBACH S. Liquid immiscible alloys[J]. Mater. Sci. Eng., 1995, 15:263-347 [2] RUDRAKSHI G B, OJHA S N. Spray forming and wear characteristics of liquid immiscible alloys[J]. J. Mater. Proc. Technol., 2007, 189(1/2/3):224-230 [3] PRATT G C. Materials for plain bearings[J]. Int. Met. Rev., 1973, 18:62-88 [4] TERIZIEFF P, LUCK R. Magnetic investigations in li-quid Al-In[J]. J. Alloys Compd., 2003, 360(1/2):205-209 [5] WANG C P, LIU X J, OHNUMA I, et al. Formation of immiscible alloy powders with egg-type microstructure[J]. Science, 2002, 297:990-993 [6] SUN Z B, WANG Y H, GUO J, et al. Liquid and solid phase separation during melt spinning and annealing in melt-spun Cu-Cr ribbons[J]. Mater. Sci. Eng., 2007, 452-453:411-416 [7] ANDREWS J B, HAYES L J, ARIKAWA Y, CORIELL S R. Microgravity solidification of immiscible alloys[J]. Mat. Res. Soc. Symp. Proc., 1999, 551:255-265 [8] NEUMANN H, PLEVACHUK Y, ALLENSTEIN F. Investigation of Marangoni convection in monotectic melts by resistance measurements[J]. Mater. Sci. Eng., 2003, 361:155-164 [9] HUANG Q, LUO X H, LI Y Y. An alloy solidification experiment conducted on Shenzhou spacecraft[J]. Adv. Spa-ce Res., 2005, 36:86-91 [10] RUDRAKSHI G B, SRIVASTAVA V C, PATHAK J P, OJHA S N. Spray forming of Al-Si-Pb alloys and their wear characteristics[J]. Mater. Sci. Eng., 2004, 383:30-38 [11] ZHAO J Z. Formation of the minor phase shell on the surface of hypermonotectic alloy powders[J]. Scripta Mater., 2006, 54:247-250 [12] DAI R R, ZHANG S G, GUO X, LI J G. Formation of core-type microstructure in Al-Bi monotectic alloys[J]. Mater. Lett., 2011, 65:322-325 [13] JIANG H X, ZHAO J Z. Effect mechanism of a dire-ct current on the solidification of immiscible alloys[J]. Chin. Phys. Lett., 2012, 29:088104 [14] ZHANG Lin, WANG Engang, ZUO Xiaowei, HE Jicheng. Effect of high magnetic field on solidified structure of Cu-80%Pb hypermonotectic alloy[J]. Acta Metall. Sin., 2008, 44:165-171(张林, 王恩刚, 左小伟, 赫冀成. 强磁场对Cu-80%Pb过偏晶合金凝固组织的影响[J]. 金属学报, 2008, 44:165-171) [15] WANG J, ZHONG Y B, WANG C, et al. Physical simulation of homogeneous Zn-Bi monotectic alloy prepared by electric-magnet compound field[J]. Acta Phys. Sin., 2011, 60:076101(王江, 钟云波, 汪超, 等. 电磁复合场制备匀质Zn-Bi偏晶合金的物理模拟[J]. 物理学报, 2011, 60:076101) [16] WANG C P, LIU X J, SHI R P, et al. Design and formation mechanism of self-organized core/shell structure composite powder in immiscible liquid system[J]. Appl. Phys. Lett., 2007, 91:141904 [17] LI H L, ZHAO J Z. Convective effect on the microstructure evolution during a liquid-liquid decomposition[J]. Appl. Phys. Lett., 2008, 92:241902 [18] YANG Zhizeng, SUN Qian, ZHAO Jiuzhou. Directional solidification of monotectic composition Al-Bi alloy[J]. Acta Metall. Sin., 2014, 50:25-31(杨志增, 孙倩, 赵九洲. Al-Bi偏晶点成分合金定向凝固过程研究[J]. 金属学报, 2014, 50:25-31) -
1. 康智强,张煜博,杨雪,冯国会,张林. Al基偏晶合金凝固过程的研究进展. 热加工工艺. 2018(24): 6-9+14 . 百度学术
2. 张煜博. Al-In偏晶合金凝固组织微观结构演变过程的研究[D]. 沈阳建筑大学. 2019. 百度学术
3. 李彦强. Pb-Al合金凝固过程、电化学性能及电、磁场影响研究[D]. 中国科学技术大学. 2023. 百度学术
4. 李聪敏. 原位制备TiCx对Al-Bi合金微观组织及摩擦磨损性能影响研究[D]. 合肥工业大学. 2023. 百度学术
5. 曹刚. TiC对Al-Bi合金材料微观组织与性能影响研究[D]. 合肥工业大学. 2022. 百度学术
-
计量
- 文章访问数: 1821
- HTML全文浏览量: 293
- PDF下载量: 733
-
被引次数:
2(来源:Crossref)
5(来源:其他)